Synthetic Applications of Zinc Borohydride
نویسندگان
چکیده
منابع مشابه
Polymer Supported Zinc Borohydride: A Stable, Efficient, Selective, and Regenerable Reducing Agent for Variety of Organic Compounds
The difficult to handle and store zinc borohydride, Zn(BH4)2, is stabilized by supporting it on polyvinylpyridine. This new mild, efficient, selective, and regenerable polymer supported borohydride reducing agent reduces a variety organic compounds such as, aldehydes, a-b-unsaturated carbonyl compounds, acid chlorides, epoxides, disu...
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In 1941 (1) the senior author entered the field of 16-substituted steroids with the view of preparing all of the three possible 16,17-epimers of natural estriol. Since that time two of these three epimers, 16-epiestriol (isoestriol-A) (2) and 17-epiestriol (3), have become available through our efforts and those of the Swiss investigators. In 1952 the present authors made an attempt to prepare ...
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The dehalogenation of a-haloketones and a-halocarbonyl compounds is an inevitable proce dure for the organic synthesis and these reductive dehalogenations have been often effected in organic syntheses. There have been various procedures for the purpose and these are obtained by zinc and acetic acid [1], sodium dithionite [2], titanium(III) chloride [3], organotin hydride [4], sodium hydrogen t...
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